INDEPENDENT NIOBIUM AND TANTALUM MINERALS DISCOVERED IN SAIMA DEPOSIT, EASTERN LIAONING
LI Jin-xuan1, WU Yue2, JU Nan2, LIU Xin2, SHI Lu2
1. Mudanjiang Natural Resources Comprehensive Survey Center, CGS, Mudanjiang 157000, Heilongjiang Province, China; 2. Shenyang Center of China Geological Survey, Shenyang 110034, China
Abstract:Through scanning electron microscopy and electron probe, independent niobium-tantalum minerals, mainly loparite, betafite and fersmite, are identified from the Saima Nb-Ta deposit in eastern Liaoning Province for the first time. The discovery solves the controversy about the existence of independent niobium-tantalum minerals in the area. According to the results of Sr-Nd-Pd isotope analysis, it is inferred that the mineralization of the niobium-tantalum deposit is related to mantle enrichment, with mixture of some crustal materials.
李建康, 李鹏, 王登红, 等. 中国铌钽矿成矿规律[J]. 科学通报, 2019, 64(15):1545-1566. Li J K, Li P, Wang D H, et al. A review of niobium and tantalum metallogenic regularity in China[J]. Chinese Science Bulletin, 2019, 64(15):1545-1566.
[2]
张培善, 杨主明, 陶克捷, 等. 我国铌钽稀土矿物学及工业利用[J]. 稀有金属, 2005, 29(2):206-210. Zhang P S, Yang Z M, Tao K J, et al. Niobian-tantalian and rare earth mineralogy in China and their industrial utilization[J]. Chinese Journal of Rare Metals, 2005, 29(2):206-210.
[3]
Fan H R, Xie Y H, Wang K Y, et al. Methane-rich fluid inclusions in skarn near the giant REE-Nb-Fe deposit at Bayan Obo, Northern China[J]. Ore Geology Reviews, 2004, 25(3/4):301-309.
[4]
Liu Y, Chakhmouradian A R, Hou Z Q, et al. Development of REE mineralization in the giant Maoniuping deposit (Sichuan, China): Insights from mineralogy, fluid inclusions, and trace-element geochemistry[J]. Mineralium Deposita, 2019, 54(5):701-718.
[5]
牛贺才, 单强, 陈小明, 等. 攀西裂谷带轻稀土矿床与地幔过程的关系[J]. 中国科学(D辑), 2002, 32(S1):33-40. Niu H C, Shan Q, Chen X M, et al. Relationship between light rare earth deposits and mantle processes in Panxi rift, China[J]. Science in China Series D:Earth Sciences, 2003, 46(S1):41-49.
[6]
周玲棣, 王扬传. 赛马和紫金山碱性杂岩体稀土元素地球化学及成因模式[J]. 地球化学, 1991(3):229-235. Zhou L L, Wang Y C. REE geochemistry and genetic model of Saima and Zhijingshan alkaline rock bodies[J]. Geochimica, 1991(3):229-235.
[7]
冉清昌, 刘学珍. 凤城碱性杂岩与有关含金刚石岩类对比的意义[J]. 长春地质学院学报, 1993, 23(3):279-285. Ran Q C, Liu X Z. Significance of contrasting between Fengcheng alkaline complex and related diamond-bearing rocks[J]. Journal of Changchun University of Earth Sciences, 1993, 23(3):279-285.
[8]
曹正琦, 侯光久. 大兴安岭北段晚中生代碱性侵入岩岩石地球化学特征及其意义[J]. 矿物岩石地球化学通报, 2009, 28(3):209-216. Cao Z Q, Hou G J. The Late Mesozoic alkaline intrusive rocks at the north of the Da Hinggan Mountains:Lithogeochemical characteristics and their implications[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2009, 28(3):209-216.
[9]
成曦晖, 徐九华, 张辉, 等. 辽东赛马-柏林川碱性岩区石英脉中的包裹体[J]. 矿床地质, 2014, 33(S1):503-504. Cheng X H, Xu J H, Zhang H, et al. The inclusions in quartz veins in the alkaline rock area of eastern Liaoning Province[J]. Mineral Deposits, 2014, 33(S1):503-504. (in Chinese)
[10]
赵正, 漆亮, 黄智龙, 等. 攀西裂谷南段鸡街碱性超基性岩矿物学与岩石化学[J]. 地学前缘, 2010, 17(2):320-335. Zhao Z, Qi L, Huang Z L, et al. A study of mineralogy and petrochemistry of Jijie alkaline-ultramafic rocks, southern part of Panxi rift[J]. Earth Science Frontiers, 2010, 17(2):320-335.
[11]
鞠楠, 张森, 毕中伟, 等. 辽宁凤城赛马铌矿床成矿岩体地球化学特征及其地质意义[J]. 世界地质, 2019, 38(1):130-139, 153. Ju N, Zhang S, Bi Z W, et al. Geochemical characteristics and geological significance of metallogenic rock bodies of Saima niobium deposit in Fengcheng, Liaoning[J]. Global Geology, 2019, 38(1): 130-139, 153.
[12]
邬斌, 王汝成, 刘晓东, 等. 辽宁赛马碱性岩体异性石化学成分特征及其蚀变组合对碱性岩浆-热液演化的指示意义[J]. 岩石学报, 2018, 34(6):1741-1757. Wu B, Wang R C, Liu X D, et al. Chemical composition and alteration assemblages of eudialyte in the Saima alkaline complex, Liaoning Province, and its implication for alkaline magmatic-hydrothermal evolution[J]. Acta Petrologica Sinica, 2018, 34(6): 1741-1757.
[13]
张轰玉, 杨占峰, 焦登铭, 等. 白云鄂博主矿霓石型铌稀土铁矿石中铌在独立矿物中的富集状态和分布规律研究[J]. 有色金属(选矿部分), 2020(1):6-12. Zhang H Y, Yang Z F, Jiao D M, et al. Distribution regularity and enrichment state of niobium in independent minerals in aegirine-type niobium rare earth iron ore in Bayan Obo main mine[J]. Nonferrous Metals (Mineral Processing Section), 2020(1):6-12.
[14]
毛朝霞, 郑常青, 毕中伟, 等. 大兴安岭地区铌钽矿找矿潜力的初步分析[J]. 地质与资源, 2016, 25(3):269-274. Mao Z X, Zheng C Q, Bi Z W, et al. Preliminary Study on the prospecting potential of niobium-tantalum deposits in Daxinganling region[J]. Geology and Resources, 2016, 25(3):269-274.
[15]
柳晓艳, 蔡剑辉, 阎国翰. 华北克拉通南缘古中元古代碱性岩岩石地球化学特征及其地质意义[J]. 矿床地质, 2010, 29(S1):1109-1110. Liu X Y, Cai J H, Yan G H. Petrogeochemical characteristics and geological significance of ancient Middle Proterozoic alkali rocks in the southern margin of North China craton[J]. Mineral Deposits, 2010, 29(S1):1109-1110. (in Chinese)